Triisobutylaluminum → Decane

HRID 258239Notes

Reaction equation

HRID 258239 reaction equation
C([Al](C[CH:11]([CH3:13])[CH3:12])CC(C)C)C(C)C.[CH2:14]=[CH2:15].C[CH:17]([CH3:21])[CH2:18][CH:19]=[CH2:20]>C1C=CC=CC=1>[CH3:14][CH2:15][CH2:20][CH2:19][CH2:18][CH2:17][CH2:21][CH2:13][CH2:11][CH3:12]

Participants

4

Reactant 2

HCID 16682931TriisobutylaluminumHCID 86745194Ethylene 4-methyl-1-pentene

Product 1

HCID 15600Decane

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

The polymerization of Example 10 was repeated except that in place of the organoaluminum oxy-compound used therein, there were used 0.1 mg atom in terms of aluminum atom of the benzene-insoluble organoaluminum oxy-compound as prepared above, 1 mmole of triisobutylaluminum and 4.2×10-4 mg atom in terms of titanium atom of the solid catalyst component [I], whereby 50.8 g of an ethylene/4-methyl-1-pentene copolymer having MFR of 0.13 g/10 min, a density of 0.904 g/cm3, an amount of decane-soluble portion of 0.35% by weight and Mw/Mn of 6.1 was obtained.

Workup

  1. customThe polymerization of Example 10
  2. customMFR of 0.13 g/10 min

Sources & evidence

ORD record
ord-c907454a4bb94a3b832c9097b6c5dc8e
Source dataset
uspto-grants-1993_11
Patent number
US05266544

Reaction notes

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