Epichlorohydrin → HCID 13420181, compound

HRID 258420Notes

Reaction equation

S([C:5]1[CH:11]=[CH:10][C:8]([CH3:9])=[CH:7][CH:6]=1)([O-])(=O)=O.[CH2:12]([CH:14]1[O:16][CH2:15]1)Cl>>[C:8]([C:5]1[CH:11]=[CH:10][C:8]([CH2:9][CH2:12][CH:14]2[O:16][CH2:15]2)=[CH:7][CH:6]=1)([CH3:10])([CH3:9])[CH3:7]

Participants

Reactant 2

HCID 7835Epichlorohydrin

HCID 85570p-Toluenesulfonate

Product 1

HCID 13420181HCID 13420181, compound

Procedure

reacting a 4-tert.butylbenzyl magnesuim halide with a stereochemically pure glycydyl tosylate or epichlorohydrin to form a single enantiomer of 4-(4'-tert.butylphenyl)-1,2-epoxybutane;

Sources & evidence

ORD record: ord-805a3019a94046929d39b4f966ec38ca
Source dataset: uspto-grants-1993_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05266721

Reaction notes

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