Ethanol → HCID 131710840、化合物

HRID 258795ノート

反応式

HRID 258795 の反応式
[CH2:1]([NH:3][C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([CH3:10])[CH:5]=1)[CH3:2].CCO[CH2:14][CH2:15][O:16][CH2:17][CH2:18]Br.C(=O)(O)[O-].[Na+].[CH2:25]([OH:27])[CH3:26]>O>[CH2:1]([N:3]([CH2:26][CH2:25][O:27][CH:17]([O:16][CH2:15][CH3:14])[CH3:18])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([CH3:10])[CH:5]=1)[CH3:2]

参加物

6

反応物 4

HCID 702EthanolHCID 7603N-ethyl-3-methylanilineHCID 516892Sodium BicarbonateHCID 70153241-Bromo-2-(2-ethoxyethoxy)ethane

生成物 1

HCID 131710840HCID 131710840、化合物

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A mixture of 67.5 g(0.5 mole) of N-ethyl-3-methyl-aniline, 98.5 g (0.5 mole) of [β-(β-ethoxy)-ethoxy]ethyl bromide, 44.1 g (0.55 mole) of sodium bicarbonate, 5.50 ml of ethanol and 145 ml of water was refluxed for 80 hours. Ethanol was removed by distillation and the oil layer was extracted with ether. The extract was dried with potassium carbonate and then ether was removed, followed by distillation of the residue oil under reduced pressure.

後処理

  1. temperaturewas refluxed for 80 hours
  2. customEthanol was removed by distillation
  3. extractionthe oil layer was extracted with ether
  4. dry with materialThe extract was dried with potassium carbonate
  5. customether was removed
  6. distillationfollowed by distillation of the residue oil under reduced pressure

出典と根拠

ORDレコード
ord-a3059631fdba4057814c471ea83120ab
出典データセット
uspto-grants-1977_07
特許番号
US04035188

反応ノート

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