Sulfuric Acid → HCID 21423227, compound

HRID 259152Notes

Reaction equation

C(S[C:4]1[CH:9]=[CH:8][C:7]([N:10]2[CH:14]=[N:13][N:12]=[N:11]2)=[CH:6][CH:5]=1)C.[CH2:15](SC1C=CC(N)=CC=1)[CH3:16].[N-:25]=[N+]=[N-].[Na+].[S:29](=[O:33])(=O)(O)O>>[CH2:15]([S:29]([C:4]1[CH:5]=[CH:6][C:7]([N:10]2[CH:14]=[N:13][N:12]=[N:11]2)=[CH:8][CH:9]=1)(=[NH:25])=[O:33])[CH3:16]

Participants

Reactant 4

HCID 1118Sulfuric Acid

HCID 33557Sodium Azide

HCID 4375354-ethylsulfanylaniline

HCID 21423244HCID 21423244, compound

Product 1

HCID 21423227HCID 21423227, compound

Procedure

Following the general procedure of Example 15, 1-[p-(ethylthio)phenyl]-1H-tetrazole (prepared from p-ethylthioaniline by the method of Example 2) is treated with sodium azide and concentrated sulfuric acid to give the S-ethyl-S-[p-(1H-tetrazole-1-yl)-phenyl]sulfoximine.

Sources & evidence

ORD record: ord-df9eac067bdd43d2b6348cc71d474ec2
Source dataset: uspto-grants-1977_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04036849

Reaction notes

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