huagongshe.com
HRID259215

反应详情

EQUATION

反应方程式

HRID 259215 的结构方程式

REACTANTS

反应物

3
结构：CC=O
HCID177

Acetaldehyde

C2H4O

结构：c1ccc(OP(Oc2ccccc2)c2ccccc2)cc1
HCID239038

Diphenyl phenylphosphonite

C18H15O2P

结构：NS(=O)(=O)N1CCCCC1
HCID276741

1-Piperidinesulfonamide

C5H12N2O2S

PRODUCTS

生成物

1
结构：CC(NS(=O)(=O)N1CCCCC1)P(=O)(Oc1ccccc1)c1ccccc1
HCID21428537

未命名化合物

收率 75%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Clc1ccccc1
溶剂HCID7964

Chlorobenzene

C6H5Cl

PROCEDURE

实验过程

This compound is obtained in 75% yield in a crude form from a mixture of equimolar quantities of diphenyl phenylphosphonite, acetaldehyde, and piperidinosulfonylamine in chlorobenzene. Recrystallization of a portion twice from acetonitrile gives a white solid product: mp 152°-165°; 31P nmr(DMSO-d6) -38.4 ppm.

WORKUP

后处理

  1. customThis compound is obtained in 75% yield in a crude form
  2. customRecrystallization of a portion twice from acetonitrile
  3. customgives a white solid product