HRID259228

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7847

Acrolein

C3H4O

HCID11583

2-Hexanone

C6H12O

HCID12993

2-Pentenal

C5H8O

HCID447466

(E)-Crotonaldehyde

C4H6O

HCID11535561

未命名化合物

PRODUCTS

生成物

HCID12609029

未命名化合物

PROCEDURE

实验过程

In the same manner but replacing acrolein with an equivalent amount of crotonaldehyde, 2-pentenal, 2-hexanal or γ-acetoxycrotonaldehyde, the following compounds of formula V, dimethyl 2-formyl-3-methylcyclopropane-1,1-dicarboxylate, dimethyl 2-formyl-3-ethylcyclopropane-1,1-dicarboxylate, dimethyl 2-formyl-3-propylcyclopropane-1,1-dicarboxylate, dimethyl 3-(acetoxymethyl)-2-formylcyclopropane-1,1-dicarboxylate are obtained, respectively.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-5e7bd1f8c36f418c8a865f4231ca12fc
来源数据集: uspto-grants-1977_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04036856
来源说明: uspto-grants-1977_07

反应 SMILES

[CH:1]([CH:3]=[CH2:4])=[O:2].[CH:5](=[O:9])/[CH:6]=[CH:7]/[CH3:8].[CH:10](=[O:15])[CH:11]=[CH:12][CH2:13][CH3:14].C[C:17](=[O:22])[CH2:18][CH2:19][CH2:20][CH3:21].[C:23]([O:26][CH2:27]/[CH:28]=[CH:29]/[CH:30]=[O:31])(=[O:25])[CH3:24]>>[CH:10]([CH:11]1[CH:13]([CH3:14])[C:12]1([C:5]([O:2][CH3:1])=[O:9])[C:23]([O:26][CH3:27])=[O:25])=[O:15].[CH:30]([CH:29]1[CH:8]([CH2:7][CH3:6])[C:28]1([C:17]([O:2][CH3:1])=[O:22])[C:27]([O:26][CH3:23])=[O:15])=[O:31].[CH:1]([CH:3]1[CH:21]([CH2:20][CH2:19][CH3:18])[C:4]1([C:10]([O:9][CH3:5])=[O:15])[C:23]([O:26][CH3:27])=[O:25])=[O:2].[C:23]([O:26][CH2:27][CH:28]1[C:3]([C:4]([O:9][CH3:5])=[O:22])([C:1]([O:15][CH3:10])=[O:2])[CH:29]1[CH:30]=[O:31])(=[O:25])[CH3:24]