HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tetrahydrofuran → 1-(5-Bromofurylideneamino)-2-oxo-imidazolidine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tetrahydrofuran | HCID 8028 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 5-Bromofuran-2-carbaldehyde | HCID 600328 | — |
| Reactant | 1-Amino-2-imidazolidinone hydrochloride | HCID 19261678 | — |
| Solvent | Water | HCID 962 | — |
| Product | 1-(5-Bromofurylideneamino)-2-oxo-imidazolidine | HCID 70571814 | — |
Reaction Steps
33.5 pts. by wt. of 2-bromofuran-5-aldehyde, dissolved in 100 pts. by vol. of THF, are added to a solution of 1-amino-2-oxo-imidazolidine hydrochloride in 350 pts. by vol. of water, which has been adjusted to pH 5 with sodium hydroxide solution, and the mixture is stirred overnight. The precipitate is filtered off, washed with water and recrystallised from methanol. 30.0 pts. by wt. of 1-(5-bromofurylideneamino)-2-oxo-imidazolidine of dec. pt. 153°-158° C. are obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04147693 |
| Source dataset | uspto-grants-1979_04 |
| ORD ID | ord-5fe05e38426c4bce8f418d26222a5c9f |
| Source note | uspto-grants-1979_04 |