HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → 1-Adamantyl 3,4-dichlorophenylthiomethyl ketone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 3,4-Dichlorobenzenethiol | HCID 79964 | — |
| Reactant | Bromomethyl tricyclo[3.3.1.13,7]dec-1-yl ketone | HCID 197820 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 1-Adamantyl 3,4-dichlorophenylthiomethyl ketone | HCID 21424044 | — |
Reaction Steps
1-adamantyl bromomethyl ketone (1.3 g.), 1.1 g. of 3,4-dichlorothiophenol and 800 mg. of anhydrous potassium carbonate in 30 ml. of acetone are stirred at reflux overnight. The solvent is then removed and 60 ml. of water is added to the reaction mixture. The product is filtered off, washed with water and recrystallized from methanol to yield 1-adamantyl 3,4-dichlorophenylthiomethyl ketone, M.P. 105°-110.5° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04036975 |
| Source dataset | uspto-grants-1977_07 |
| ORD ID | ord-5fa6384611b3406fa60c6e11270986ca |
| Source note | uspto-grants-1977_07 |