Acetone → 4-Acetyl m-terphenyl

HRID 25931Notes

Reaction equation

[N+]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)([O-])=O.[CH3:10][C:11]([CH3:13])=[O:12]>>[C:11]([C:13]1[CH:8]=[CH:9][C:4]([C:4]2[CH:9]=[CH:8][CH:7]=[C:6]([C:4]3[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=3)[CH:5]=2)=[CH:5][CH:6]=1)(=[O:12])[CH3:10]

Participants

Reactant 2

HCID 180Acetone

HCID 7416Nitrobenzene

Product 1

HCID 123784054-Acetyl m-terphenyl

Procedure

Nitrobenzene is stripped with steam and the solid residue is dissolved into acetone. After filtration and the acetone evaporation, 400 g of crude product is obtained.

Workup

filtrationAfter filtration
customthe acetone evaporation

Sources & evidence

ORD record: ord-160d52d13306401890cc3c52431d6e5b
Source dataset: uspto-grants-1979_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04147728

Reaction notes

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