HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyldithiocarbamic acid, dimethylamine → 3,4-(Methylenedioxy)-alpha-(nitromethyl)benzyl dimethyldithiocarbamate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyldithiocarbamic acid, dimethylamine | HCID 11728 | — |
| Reactant | 5-(2-Nitroethenyl)-1,3-benzodioxole | HCID 94945 | — |
| Solvent | Carbon Disulfide | HCID 6348 | — |
| Product | 3,4-(Methylenedioxy)-alpha-(nitromethyl)benzyl dimethyldithiocarbamate | HCID 21324627 | — |
Reaction Steps
As in Example 17, reaction of 3,4-(methylenedioxy)-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 3,4-(methylenedioxy)-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 122° - 124° C. when recrystallized without heating from acetone-ethanol solution.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04038288 |
| Source dataset | uspto-grants-1977_07 |
| ORD ID | ord-8179e480f2404ba4b2b8164085e41c6e |
| Source note | uspto-grants-1977_07 |