Dimethyldithiocarbamic acid, dimethylamine → HCID 21324612, compound

HRID 259468Notes

Reaction equation

HRID 259468 reaction equation
[N+:1]([CH:4]=[CH:5][C:6]1[S:7][CH:8]=[CH:9][CH:10]=1)([O-:3])=[O:2].[CH3:11][N:12]([CH3:16])[C:13](=[S:15])[S-:14].C[NH2+]C>C(=S)=S>[CH3:11][N:12]([CH3:16])[C:13](=[S:14])[S:15][CH:5]([CH2:4][N+:1]([O-:3])=[O:2])[C:6]1[S:7][CH:8]=[CH:9][CH:10]=1

Participants

4

Reactant 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 955862-(2-Nitro-vinyl)-thiophene

Product 1

HCID 21324612HCID 21324612, compound

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of 2-(2-nitrovinyl)thiophene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave α-(nitromethyl)-2-thenyl dimethyldithiocarbamate melting at 88°-90° C. when recrystallized without heating from acetone-ethanol solution.

Sources & evidence

ORD record
ord-55e397b7c94c4b459486a8163a443477
Source dataset
uspto-grants-1977_07
Patent number
US04038288

Reaction notes

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