Dimethyldithiocarbamic acid, dimethylamine → 5-Chloro-alpha-(nitromethyl)-2-thenyl dimethyldithiocarbamate

HRID 259469Notes

Reaction equation

HRID 259469 reaction equation
[Cl:1][C:2]1[S:3][C:4]([CH:7]=[CH:8][N+:9]([O-:11])=[O:10])=[CH:5][CH:6]=1.[CH3:12][N:13]([CH3:17])[C:14](=[S:16])[S-:15].C[NH2+]C>C(=S)=S>[CH3:12][N:13]([CH3:17])[C:14](=[S:15])[S:16][CH:7]([CH2:8][N+:9]([O-:11])=[O:10])[C:4]1[S:3][C:2]([Cl:1])=[CH:6][CH:5]=1

Participants

4

Reactant 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 818880HCID 818880, compound

Product 1

HCID 213245915-Chloro-alpha-(nitromethyl)-2-thenyl dimethyldithiocarbamate

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of 2-chloro-5-(2-nitrovinyl)thiophene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 5-chloro-α-(nitromethyl)-2-thenyl dimethyldithiocarbamate melting at 76°-77° C., after recrystallization without heating from acetone-methanol solution.

Sources & evidence

ORD record
ord-9b061eac1d9443a292de08dceb97ff79
Source dataset
uspto-grants-1977_07
Patent number
US04038288

Reaction notes

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