Hexamethylphosphorous triamide → HCID 178420727, compound

HRID 259488Notes

Reaction equation

HRID 259488 reaction equation
[NH:1]1[CH2:13][CH2:12][CH2:11][NH:10][CH2:9][CH2:8][NH:7][CH2:6][CH2:5][NH:4][CH2:3][CH2:2]1.CN(C)[P:16](N(C)C)N(C)C>>[N:4]12[PH:16]34[N:10]([CH2:9][CH2:8][N:7]3[CH2:6][CH2:5]1)[CH2:11][CH2:12][CH2:13][N:1]4[CH2:2][CH2:3]2

Participants

3

Reactant 2

HCID 15355Hexamethylphosphorous triamideHCID 114787231,4,7,10-TETRAAZACYCLOTRIDECANE

Product 1

HCID 178420727HCID 178420727, compound

Procedure

A mixture of 4.00 g (21.5 mmol) of 1,4,7,10-tetraazacyclotridecane and 3.50 g (21.5 mmol) of hexamethylphosphorous triamide is heated for 2 hr under nitrogen at 125° and then distilled under vacuum to give 3.84 g (83%) of clear, colorless, viscous liquid 1,4,8,11-tetraaza-14-phosphatetracyclo[6.5.1.04,14.011,14 ]tetradecane, bp 92° (0.30 mm).

Workup

  1. temperatureis heated for 2 hr under nitrogen at 125°
  2. distillationdistilled under vacuum

Sources & evidence

ORD record
ord-2867beae6ab64cc68fd333be26bf480c
Source dataset
uspto-grants-1977_07
Patent number
US04038312

Reaction notes

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