HuagongsheHuagongshe Chemistry Print Report · For research reference only
(Z)-3-(3-nitro-4-methoxyphenyl)-2-(3,4,5-trimethoxyphenyl)-prop-2-ene-nitrile → (E)-3-(3-nitro-4-methoxyphenyl)-2-(3,4,5-trimethoxyphenyl)-prop-2-ene-nitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (Z)-3-(3-nitro-4-methoxyphenyl)-2-(3,4,5-trimethoxyphenyl)-prop-2-ene-nitrile | HCID 10619131 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | (E)-3-(3-nitro-4-methoxyphenyl)-2-(3,4,5-trimethoxyphenyl)-prop-2-ene-nitrile | HCID 10666833 | 49.8% |
Reaction Steps
2.0 g of (Z)-3-(3-nitro-4-methoxyphenyl)-2-(3,4,5-trimethoxyphenyl)-prop-2-ene-nitrile were dissolved in 500 ml of acetonitrile and exposed to visible light rays for 60 minutes. The reaction liquid was concentrated and crystallized from ethyl acetate to obtain 996 mg of the intended compound. The yield was 49%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05525632 |
| Source dataset | uspto-grants-1996_06 |
| ORD ID | ord-a45221c179af471c9e73e628a6b49ad6 |
| Source note | uspto-grants-1996_06 |