HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → 2-(3-Butenyloxy)-4,4'-dinitrobiphenyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Homoallyl bromide | HCID 21241 | — |
| Reactant | 4,4'-Dinitro-2-hydroxybiphenyl | HCID 14250152 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 2-(3-Butenyloxy)-4,4'-dinitrobiphenyl | HCID 22401618 | 41.4% |
Reaction Steps
Next, 10.4 g of the 4,4'-dinitro-2-hydroxybiphenyl thus obtained was dissolved in 95 mL dry acetone. 5.52 g of potassium carbonate and 7.56 g of 4-bromo-1-butene were added, and the resulting mixture was heated under reflux for 71 hours. Workup by the usual methods gave 5.20 g of 2-(3-butenyloxy)-4,4'-dinitrobiphenyl as a light yellow powder.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05527862 |
| Source dataset | uspto-grants-1996_06 |
| ORD ID | ord-2852d655897a4f89b57272b85bd3da9b |
| Source note | uspto-grants-1996_06 |