HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Hydroxide → Diethyl 2-(3-butenyloxy)terephthalate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | Homoallyl bromide | HCID 21241 | — |
| Reactant | Diethyl 2-hydroxybenzene-1,4-dicarboxylate | HCID 22401614 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Diethyl 2-(3-butenyloxy)terephthalate | HCID 22401611 | 39.9% |
Reaction Steps
3.55 g of this diethyl hydroxyterephthalate was dissolved in 100 mL dimethylformamide and combined with 640 mg of crushed sodium hydroxide. 4.03 g of 4-bromo-1-butene dissolved in 20 mL of dimethylformamide was added dropwise in while cooling on an ice bath. After stirring the reaction for 16 hours, purification by the usual methods gave 1.74 g of diethyl 2-(3-butenyloxy)terephthalate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05527862 |
| Source dataset | uspto-grants-1996_06 |
| ORD ID | ord-c7bd1eecbcbf48718644374b9d43c475 |
| Source note | uspto-grants-1996_06 |