HuagongsheHuagongshe Chemistry Print Report · For research reference only
P-Xylene → 3-(2,5-Dimethylphenyl)-1,1-dichloro-1-silabutane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | P-Xylene | HCID 7809 | — |
| Reactant | Dichloro(prop-2-enyl)silane | HCID 77536 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Product | 3-(2,5-Dimethylphenyl)-1,1-dichloro-1-silabutane | HCID 14972039 | 81% |
Reaction Steps
In the same apparatus and procedures as Example 1, 0.9 g (0.007 mol) of aluminum chloride and 37 g (0.349 mol) of p-xylene were reacted with 10 g (0.07 mol) of allyldichlorosilane at 0° C. for 1.5 hrs. Vacuum distillation of the solution gave 9.1 g (81%) of 3-(2,5-dimethylphenyl)-1,1-dichloro-1-silabutane (boiling point: 86°-9° C./0.6 mmHg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05527938 |
| Source dataset | uspto-grants-1996_06 |
| ORD ID | ord-26440521e4d04b1f82010ccd6d3f2a85 |
| Source note | uspto-grants-1996_06 |