2-(4-Bromo-3-hydroxyphenyl)-2-methylnonane → 2-Bromo-5-(2-methyloctan-2-YL)phenol

HRID 26082Notes

Reaction equation

HRID 26082 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]([CH3:17])([CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15]C)[CH3:9])=[CH:4][C:3]=1[OH:18].OC1C=C(C(C)(CCCCCCC)C)C=CC=1>>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]([CH3:17])([CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])[CH3:9])=[CH:4][C:3]=1[OH:18]

Participants

3

Reactant 2

HCID 204968492-(4-Bromo-3-hydroxyphenyl)-2-methylnonaneHCID 204969203-(1,1-Dimethyloctyl)phenol

Product 1

HCID 127881872-Bromo-5-(2-methyloctan-2-YL)phenol

Procedure

In like manner, 2-(4-bromo-3-hydroxyphenyl)-2-methylnonane is prepared in 82% (8.5 g.) yield as an oil from 7.8 g. (0.033 mol.) of 2-(3-hydroxyphenyl)-2-methylnonane:

Workup

  1. customyield as an oil from 7.8 g

Sources & evidence

ORD record
ord-4d2510bbce894fd394098e538fdbfcac
Source dataset
uspto-grants-1979_04
Patent number
US04147872

Reaction notes

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