(E)-4-methoxybenzyl 4-[3-(2-nonenoyl)-1-indolyl]butyrate → (E)-4-[3-(2-undecenoyl)-1-indolyl]butyric acid

HRID 260858Notes

Reaction equation

HRID 260858 reaction equation
[C:1]([C:13]1[C:21]2[C:16](=[CH:17][CH:18]=[CH:19][CH:20]=2)[N:15]([CH2:22][CH2:23][CH2:24][C:25]([O:27]CC2C=CC(OC)=CC=2)=[O:26])[CH:14]=1)(=[O:12])/[CH:2]=[CH:3]/[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].C(C1C2C(=CC=CC=2)N(CCCC(OCC2C=CC(OC)=CC=2)=O)C=1)(=O)/C=C/CCCCCC>>[C:1]([C:13]1[C:21]2[C:16](=[CH:17][CH:18]=[CH:19][CH:20]=2)[N:15]([CH2:22][CH2:23][CH2:24][C:25]([OH:27])=[O:26])[CH:14]=1)(=[O:12])/[CH:2]=[CH:3]/[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

Participants

3

Reactant 2

HCID 22400455(E)-4-methoxybenzyl 4-[3-(2-nonenoyl)-1-indolyl]butyrateHCID 22400543(E)-4-methoxybenzyl 4-[3-(2-undecenoyl)-1-indolyl]butyrate

Product 1

HCID 22400558(E)-4-[3-(2-undecenoyl)-1-indolyl]butyric acid

Procedure

The procedure of Ex. 45 was repeated except that (E)-4-methoxybenzyl 4-[3-(2-undecenoyl)-1-indolyl]butyrate obtained in Ex. 48 was used in place of (E)-4-methoxybenzyl 4-[3-(2-none-noyl)-1-indolyl]butyrate to give (E)-4-[3-(2-undecenoyl)-1-indolyl]butyric acid.

Workup

  1. customobtained in Ex

Sources & evidence

ORD record
ord-84f847eaec974b7e8d54b6ff7ddfd411
Source dataset
uspto-grants-1996_06
Patent number
US05530019

Reaction notes

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