HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Naphthaldehyde → 1-Naphthaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Naphthaldehyde | HCID 6195 | — |
| Reactant | Carbamic acid, N,N-dimethyl-, ethyl ester | HCID 12709 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Product | 1-Naphthaldehyde | HCID 6195 | — |
| Product | Methyl naphthyl urethane | HCID 20396153 | — |
Reaction Steps
At 160° C. and 100 mm Hg, 14 g of alpha-naphthal and 9 g of dimethyl urethane were reacted in presence of 0.7 g of anhydrous AlCl3. The reaction was continued for 6 hours, removing the methanol formed during the reaction. A 28% conversion of naphthal was obtained, with practically complete selectivity to naphthyl-methyl-urethane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04163861 |
| Source dataset | uspto-grants-1979_08 |
| ORD ID | ord-20423e548c9246b9937b955f835ebbeb |
| Source note | uspto-grants-1979_08 |