HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Naphthol → 1-Naphthol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Naphthol | HCID 7005 | — |
| Reactant | Carbamic acid, N,N-dimethyl-, ethyl ester | HCID 12709 | — |
| Product | 1-Naphthol | HCID 7005 | — |
| Product | Methyl naphthyl urethane | HCID 20396153 | — |
Reaction Steps
At 170° C. and 100 mm Hg, 14 g of alpha-naphthol and 18 g of dimethyl urethane were reacted in the presence of 1.5 g of titanium tetra-isopropylate. In 5 hours a 32% convertion of naphthol was obtained, with total selectivity to methyl naphthyl urethane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04163861 |
| Source dataset | uspto-grants-1979_08 |
| ORD ID | ord-43b28b9a7dcf45dd9212d577b5b699f7 |
| Source note | uspto-grants-1979_08 |