Dimethyldithiocarbamic acid, dimethylamine → 4-Acetoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

HRID 26145Notes

Reaction equation

HRID 26145 reaction equation
[C:1]([O:4][C:5]1[CH:15]=[CH:14][C:8]([CH:9]=[CH:10][N+:11]([O-:13])=[O:12])=[CH:7][CH:6]=1)(=[O:3])[CH3:2].[CH3:16][N:17]([CH3:21])[C:18](=[S:20])[S-:19].C[NH2+]C>C(=S)=S>[CH3:16][N:17]([CH3:21])[C:18](=[S:19])[S:20][CH:9]([CH2:10][N+:11]([O-:13])=[O:12])[C:8]1[CH:14]=[CH:15][C:5]([O:4][C:1](=[O:3])[CH3:2])=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 3258834-Acetoxy-beta-nitrostyrene

Product 1

HCID 213246054-Acetoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of 4-acetoxy-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 4-acetoxy-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 116° C.-118° C. after recrystallization without heating from acetone-methanol solution.

Sources & evidence

ORD record
ord-5ad114d4af5b45c98cdcf588a68fc2c3
Source dataset
uspto-grants-1979_04
Patent number
US04148795

Reaction notes

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