HCID 53974068, compound → HCID 53667781, compound

HRID 261516Notes

Reaction equation

HRID 261516 reaction equation
[Cl:1][C:2]1[CH:21]=[CH:20][CH:19]=[C:18]([Cl:22])[C:3]=1[NH:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[C:11](=[O:17])[C:12]([O:14][CH2:15][CH3:16])=[O:13].ClC1C=CC=C(Cl)C=1NC1C=CC=CC=1C(=O)C(OC)=O>>[Cl:1][C:2]1[CH:21]=[CH:20][CH:19]=[C:18]([Cl:22])[C:3]=1[NH:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[CH:11]([OH:17])[C:12]([O:14][CH2:15][CH3:16])=[O:13]

Participants

3

Reactant 2

HCID 53974068HCID 53974068, compoundHCID 54013338HCID 54013338, compound

Product 1

HCID 53667781HCID 53667781, compoundYield 86%

Procedure

The same procedures as in the Step 3 of Example 1 were repeated except that 3.42 g of ethyl 2-(2,6-dichloroanilino)-phenylglyoxylate were employed instead of 3.24 g of methyl 2-(2,6-dichloroanilino)phenylglyoxylate, thereby yielding 2.9 g of ethyl 2-(2,6-dichloroanilino)phenylglycolate m.p. 154.5°-156.0° C. Yield: 86% of theoretical amount

Sources & evidence

ORD record
ord-8918508c920f402a98c02b774ac83715
Source dataset
uspto-grants-1979_08
Patent number
US04166128

Reaction notes

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