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HRID261598

反应详情

EQUATION

反应方程式

HRID 261598 的结构方程式

REACTANTS

反应物

2
结构：O=Cc1ccc(C(=O)O)cc1
HCID12088

4-Carboxybenzaldehyde

C8H6O3

结构：CCC1(C(C)=O)CC1
HCID14200857

1-(1-Ethylcyclopropyl)ethan-1-one

C7H12O

PRODUCTS

生成物

1
结构：CCC1(C(=O)C=Cc2ccc(C(=O)O)cc2)CC1
HCID53946672

未命名化合物

PROCEDURE

实验过程

2-(4-Carboxyphenyl)vinyl 1-ethylcyclopropyl ketone [III; Ar is 4--HO2CC6H4, R is C2H5 ] was prepared from 67.2 g. of 1-ethylcyclopropyl methyl ketone and 90 g. of p-carboxybenzaldehyde according to the procedure described above in Preparation A1, affording 40 g., m.p. 183.5°-184.5° C. when recrystallized from acetonitrile and then repeatedly from isopropyl alcohol.

WORKUP

后处理

  1. customaffording 40 g
  2. custom, m.p. 183.5°-184.5° C. when recrystallized from acetonitrile