HRID261726

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID10942334

Methanol, sodium salt

CH3NaO

结构：[Cl][Cu].c1ccc2c(c1)-c1nc-2nc2[nH]c(nc3nc(nc4[nH]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21

HCID136395184

未命名化合物

PRODUCTS

生成物

结构：[Cu].c1ccc2c(c1)C1=NC2=NC2=NC(=NC3=NC(=NC4=NC(=N1)c1ccccc14)c1ccccc13)c1ccccc12

HCID475701

未命名化合物

PROCEDURE

实验过程

After the addition of sodium methoxide add 1.5 grams pigmentary mono-chloro-copper phthalocyanine. Finally raise the temperature to reflux and reflux 8 hours. After reflux, filter, wash with methanol and then water. The pigment is purified in the manner of Example 7 to give 28 grams of pigmentary alpha copper phthalocyanine.

WORKUP

后处理

temperatureFinally raise the temperature
temperatureto reflux
temperaturereflux 8 hours
temperatureAfter reflux
filtrationfilter
washwash with methanol
customThe pigment is purified in the manner of Example 7

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-5bd96b8d947a45858c22b7441ef9e400
来源数据集: uspto-grants-1979_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04152171
来源说明: uspto-grants-1979_05

反应 SMILES

C[O-].[Na+].Cl[Cu:5].[CH:6]1[CH:7]=[CH:8][C:9]2[C:10](=[C:12]3[N:44]=[C:43]4[N:45]=[C:36]([C:37]5[CH:38]=[CH:39][CH:40]=[CH:41][C:42]=54)[N:35]=[C:33]4[NH:34][C:26]([C:27]5[CH:28]=[CH:29][CH:30]=[CH:31][C:32]=54)=[N:25][C:23]4=[N:24][C:16]([C:17]5[CH:18]=[CH:19][CH:20]=[CH:21][C:22]=54)=[N:15][C:14]=2[NH:13]3)[CH:11]=1>>[CH:6]1[CH:11]=[C:10]2[C:12]3[N:13]=[C:14]([C:9]2=[CH:8][CH:7]=1)[N:15]=[C:16]1[C:17]2[C:22]([C:23](=[N:24]1)[N:25]=[C:26]1[C:27]4[C:32]([C:33](=[N:34]1)[N:35]=[C:36]1[C:37]5[C:42]([C:43](=[N:45]1)[N:44]=3)=[CH:41][CH:40]=[CH:39][CH:38]=5)=[CH:31][CH:30]=[CH:29][CH:28]=4)=[CH:21][CH:20]=[CH:19][CH:18]=2.[Cu:5]