HuagongsheHuagongshe Chemistry Print Report · For research reference only
p-Toluidine → N-(p-phenylbenzylidene)-p-methylaniline
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | p-Toluidine | HCID 7813 | — |
| Reactant | (1,1'-Biphenyl)-4-carboxaldehyde | HCID 76689 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | N-(p-phenylbenzylidene)-p-methylaniline | HCID 13017554 | — |
Reaction Steps
p-toluidine (0.20 mole), 4-biphenylaldehyde (0.20 mole), and IRC-50 (weakly acidic) ion exchange resin (0.5 g.) are azeotropically refluxed in toluene (150 cc). The required amount of water is removed after about 3 hours. The solvent is removed on the rotary, and the residue is recrystallized with 95% ethanol to yield N-[(p-phenyl)benzylidene]-p-methylaniline. m.p. 137°-139° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04152452 |
| Source dataset | uspto-grants-1979_05 |
| ORD ID | ord-a900ef8de75a40729911d326bbceac00 |
| Source note | uspto-grants-1979_05 |