HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 262924Generated: October 27, 2026
1,11-Dibromoundecane → Pentadecane, 1-bromo-14-methyl-
https://huagongshe.com/reaction/262924
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 1,11-Dibromoundecane | HCID 85551 | — |
| Reactant | HCID 178418529 | HCID 178418529 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | Pentadecane, 1-bromo-14-methyl- | HCID 10881292 | — |
Reaction Steps
By a procedure analogous to that described in Example 1, 3-methylbutylmagnesium bromide in tetrahydrofuran is reacted with 34.5 g. of 1,11-dibromoundecane and 0.2 g. of Li2CuCl4 in 75 ml. tetrahydrofuran. After one hour stirring at -10° C., the solution is evaporated and the resultant oil is distilled in vacuo to yield the colorless 14-methyl pentadecyl bromide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04154756 |
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| Source dataset | uspto-grants-1979_05 |
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| ORD ID | ord-eabe533532824d7bbda9677ba465f256 |
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| Source note | uspto-grants-1979_05 |
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