Thionyl Chloride → 4-(4-Chlorophenoxy)-phenoxy-acetyl chloride

HRID 263085Notes

Reaction equation

HRID 263085 reaction equation
[Cl:1][C:2]1[CH:19]=[CH:18][C:5]([O:6][C:7]2[CH:17]=[CH:16][C:10]([O:11][CH2:12][C:13](O)=[O:14])=[CH:9][CH:8]=2)=[CH:4][CH:3]=1.S(Cl)([Cl:22])=O>C1C=CC=CC=1>[Cl:1][C:2]1[CH:19]=[CH:18][C:5]([O:6][C:7]2[CH:17]=[CH:16][C:10]([O:11][CH2:12][C:13]([Cl:22])=[O:14])=[CH:9][CH:8]=2)=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 24386Thionyl ChlorideHCID 35728694-(4-Chlorophenoxy)-phenoxy-acetic acid

Product 1

HCID 213180704-(4-Chlorophenoxy)-phenoxy-acetyl chloride

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

A mixture of 8.3 g (0.0298 mol) of 4-(4-chlorophenoxy)-phenoxy-acetic acid (CRL 40 333) prepared as indicated in Example 19 and of 10.8 ml (0.1500 mol) of thionyl chloride is heated to the reflux temperature for 30 minutes. After having taken up the reaction mixture in benzene and evaporated the solution to dryness under reduced pressure, 8.7 g of a beige powder are obtained.

Workup

  1. customprepared
  2. temperatureis heated to the reflux temperature for 30 minutes
  3. customevaporated the solution to dryness under reduced pressure, 8.7 g of a beige powder
  4. customare obtained

Sources & evidence

ORD record
ord-f398d9ba133143fb98f76589262f02e3
Source dataset
uspto-grants-1979_05
Patent number
US04156011

Reaction notes

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