HRID2641

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11094753

(S)-(+)-2-Nonanol

C9H20O

结构：CCCCCCC[C@H]1CC[C@H]([SiH]2CCC(c3cc(F)c(O)c(F)c3)CC2)CC1

HCID178418463

未命名化合物

PRODUCTS

生成物

结构：CCCCCCC[C@@H](C)Oc1c(F)cc([C@H]2CC[Si@H]([C@H]3CC[C@H](CCCCCCC)CC3)CC2)cc1F

HCID178418354

未命名化合物

PROCEDURE

实验过程

The general procedure of Example 1 was repeated using 4-(4-(trans-4-n-heptylcyclohexyl)-4-silacyclohexyl)-2,6-difluorophenol and (S)-2-nonanol, thereby obtaining the intended compound.

WORKUP

后处理

customobtaining the intended compound

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-79a844ae48a5409c8f92ead50c3e3c88
来源数据集: uspto-grants-1998_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05730902
来源说明: uspto-grants-1998_03

反应 SMILES

[CH2:1]([C@H:8]1[CH2:13][CH2:12][C@H:11]([SiH:14]2[CH2:19][CH2:18][CH:17]([C:20]3[CH:25]=[C:24]([F:26])[C:23]([OH:27])=[C:22]([F:28])[CH:21]=3)[CH2:16][CH2:15]2)[CH2:10][CH2:9]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[CH3:29][C@H:30](O)[CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37]>>[CH2:1]([C@H:8]1[CH2:13][CH2:12][C@H:11]([Si@H:14]2[CH2:19][CH2:18][C@H:17]([C:20]3[CH:25]=[C:24]([F:26])[C:23]([O:27][C@H:30]([CH3:29])[CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37])=[C:22]([F:28])[CH:21]=3)[CH2:16][CH2:15]2)[CH2:10][CH2:9]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]