(S)-(+)-2-Nonanol → HCID 178418354, compound

HRID 2641Notes

Reaction equation

[CH2:1]([C@H:8]1[CH2:13][CH2:12][C@H:11]([SiH:14]2[CH2:19][CH2:18][CH:17]([C:20]3[CH:25]=[C:24]([F:26])[C:23]([OH:27])=[C:22]([F:28])[CH:21]=3)[CH2:16][CH2:15]2)[CH2:10][CH2:9]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[CH3:29][C@H:30](O)[CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37]>>[CH2:1]([C@H:8]1[CH2:13][CH2:12][C@H:11]([Si@H:14]2[CH2:19][CH2:18][C@H:17]([C:20]3[CH:25]=[C:24]([F:26])[C:23]([O:27][C@H:30]([CH3:29])[CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37])=[C:22]([F:28])[CH:21]=3)[CH2:16][CH2:15]2)[CH2:10][CH2:9]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]

Participants

Reactant 2

HCID 11094753(S)-(+)-2-Nonanol

HCID 178418463HCID 178418463, compound

Product 1

HCID 178418354HCID 178418354, compound

Procedure

The general procedure of Example 1 was repeated using 4-(4-(trans-4-n-heptylcyclohexyl)-4-silacyclohexyl)-2,6-difluorophenol and (S)-2-nonanol, thereby obtaining the intended compound.

Workup

customobtaining the intended compound

Sources & evidence

ORD record: ord-79a844ae48a5409c8f92ead50c3e3c88
Source dataset: uspto-grants-1998_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05730902

Reaction notes

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