Nonan-2R-ol → HCID 178418480, compound

HRID 2642Notes

Reaction equation

HRID 2642 reaction equation
[CH2:1]([Si:8]1(C2C=CC=CC=2)[CH2:13][CH2:12][CH:11]([C:14]2[CH:19]=[CH:18][C:17]([C:20]3[CH:25]=[C:24]([F:26])[C:23]([OH:27])=[C:22]([F:28])[CH:21]=3)=[CH:16][CH:15]=2)[CH2:10][CH2:9]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[CH3:35][C@@H:36](O)[CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43]>>[CH2:1]([Si@H:8]1[CH2:13][CH2:12][C@H:11]([C:14]2[CH:19]=[CH:18][C:17]([C:20]3[CH:21]=[C:22]([F:28])[C:23]([O:27][C@@H:36]([CH3:35])[CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43])=[C:24]([F:26])[CH:25]=3)=[CH:16][CH:15]=2)[CH2:10][CH2:9]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]

Participants

3

Reactant 2

HCID 11286536Nonan-2R-olHCID 22437474HCID 22437474, compound

Product 1

HCID 178418480HCID 178418480, compound

Procedure

The general procedure of Example 1 was repeated using 4-(4-(4-n-heptyl-4-phenyl-4-silacyclohexyl)phenyl) -2,6-difluorophenol and (R)-2-nonanol, thereby obtaining the intended compound.

Workup

  1. customobtaining the intended compound

Sources & evidence

ORD record
ord-72fab4fbc2a4453fa699034540dc6310
Source dataset
uspto-grants-1998_03
Patent number
US05730902

Reaction notes

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