4-(4-(4-n-Pentyl-4-phenyl-4-silacyclohexyl)phenyl)-2,6-difluorophenol → HCID 178418434, compound

HRID 2645Notes

Reaction equation

HRID 2645 reaction equation
[CH2:1]([Si:6]1(C2C=CC=CC=2)[CH2:11][CH2:10][CH:9]([C:12]2[CH:17]=[CH:16][C:15]([C:18]3[CH:23]=[C:22]([F:24])[C:21]([OH:25])=[C:20]([F:26])[CH:19]=3)=[CH:14][CH:13]=2)[CH2:8][CH2:7]1)[CH2:2][CH2:3][CH2:4][CH3:5].[F:33][C@@H:34]([CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44])[CH2:35]O>>[CH2:1]([Si@H:6]1[CH2:7][CH2:8][C@H:9]([C:12]2[CH:17]=[CH:16][C:15]([C:18]3[CH:19]=[C:20]([F:26])[C:21]([O:25][CH2:35][C@H:34]([F:33])[CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44])=[C:22]([F:24])[CH:23]=3)=[CH:14][CH:13]=2)[CH2:10][CH2:11]1)[CH2:2][CH2:3][CH2:4][CH3:5]

Participants

3

Reactant 2

HCID 224374634-(4-(4-n-Pentyl-4-phenyl-4-silacyclohexyl)phenyl)-2,6-difluorophenolHCID 22857780HCID 22857780, compound

Product 1

HCID 178418434HCID 178418434, compound

Procedure

The general procedure of Example 1 was repeated using 4-(4-(4-n-pentyl-4-phenyl-4-silacyclohexyl)phenyl) -2,6-difluorophenol and (S)-2-fluoro-1-decanol, thereby obtaining the intended compound.

Workup

  1. customobtaining the intended compound

Sources & evidence

ORD record
ord-a4163a4ffca54f15a71dce74978d3a8a
Source dataset
uspto-grants-1998_03
Patent number
US05730902

Reaction notes

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