Sodium Methoxide → HCID 21323432, compound

HRID 26530Notes

Reaction equation

HRID 26530 reaction equation
[CH3:1][O:2][C:3]1[CH:20]=[CH:19][C:6]2[CH:7]=[CH:8][N:9]3[C:14](S(C)(=O)=O)=[N:13][N:12]=[C:10]3[CH2:11][C:5]=2[CH:4]=1.[CH3:21][O-:22].[Na+]>>[CH3:21][O:22][C:14]1[N:9]2[C:10]([CH2:11][C:5]3[CH:4]=[C:3]([O:2][CH3:1])[CH:20]=[CH:19][C:6]=3[CH:7]=[CH:8]2)=[N:12][N:13]=1

Participants

3

Reactant 2

HCID 10942334Sodium MethoxideHCID 213233199-methoxy-3-methylsulfonyl-11H-s-triazolo[3,4-b][3]benzazepine

Product 1

HCID 21323432HCID 21323432, compound

Procedure

The reaction of 9-methoxy-3-methylsulfonyl-11H-s-triazolo[3,4-b][3]benzazepine with sodium methoxide yielded 3,9-dimethoxy-11H-s-triazolo[3,4-b][3]benzazepine. Colorless needles (as recrystallized from aqueous acetone), melting point: 176°-177° C.

Sources & evidence

ORD record
ord-f126afe44c914a8ca53dd0a78cc3ac1e
Source dataset
uspto-grants-1979_04
Patent number
US04150139

Reaction notes

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