m-Chloroperbenzoic acid → HCID 86751073, compound

Participants

Reaction Steps

1.12 g (4.74 mmol) of 72% 3-chloroperbenzoic acid are added to a solution of 0.46 g (1.16 mmol) of the compound obtained in Example 1 in 30 ml of dichloromethane. The reaction mixture is stirred at room temperature for 5 hours. The solid formed during the course of the reaction is filtered off. After conventional treatment of the organic phase and purification by chromatography on silica gel twice (eluant: hexane/ethyl acetate, 3:2), 0.146 mg (0.354 mmol) of the expected compound is obtained in the form of a mousse.

Provenance & Evidence