4-Propyl-4-phenyl-4-silacyclohexanone → HCID 178418359, compound

HRID 2655Notes

Reaction equation

HRID 2655 reaction equation
C([Si:4]1([C:11]2[CH:16]=[CH:15]C=CC=2)[CH2:9][CH2:8][C:7](=O)[CH2:6][CH2:5]1)CC.Br[C:18]1[CH:23]=[C:22](F)[C:21]([C:25]([Cl:28])=[CH:26][Cl:27])=[C:20](F)[CH:19]=1>>[CH2:11]([Si@H:4]1[CH2:5][CH2:6][C@H:7]([C:18]2[CH:23]=[CH:22][C:21]([C:18]3[CH:23]=[CH:22][C:21]([C:25]([Cl:28])=[CH:26][Cl:27])=[CH:20][CH:19]=3)=[CH:20][CH:19]=2)[CH2:8][CH2:9]1)[CH2:16][CH3:15]

Participants

3

Reactant 2

HCID 118313174-Propyl-4-phenyl-4-silacyclohexanoneHCID 539779734-Bromo-2,6-difluoro-1-(1,2-dichlorovinyl)benzene

Product 1

HCID 178418359HCID 178418359, compound

Procedure

The general procedure of Example 35 was repeated using 4-propyl-4-phenyl-4-silacyclohexanone instead of 4-pentyl-4-phenyl-4-silacyclohexanone, and 4-bromo-2,6-difluoro-1-(1,2-dichlorovinyl)benzene instead of 4-bromo-2,6-difluoro-1-(2,2-difluorovinyloxy)benzene, thereby obtaining the intended compound.

Workup

  1. customobtaining the intended compound

Sources & evidence

ORD record
ord-db385b2cb2e1457ba6d59349cf5dd028
Source dataset
uspto-grants-1998_03
Patent number
US05730901

Reaction notes

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