4-Propyl-4-phenyl-4-silacyclohexanone → HCID 178418243, compound

HRID 2656Notes

Reaction equation

HRID 2656 reaction equation
C([Si:4]1([C:11]2[CH:16]=[CH:15]C=CC=2)[CH2:9][CH2:8][C:7](=O)[CH2:6][CH2:5]1)CC.Br[C:18]1[CH:23]=[CH:22][C:21]([O:24][C:25]([F:29])=[C:26]([F:28])[F:27])=[C:20]([F:30])[CH:19]=1>>[CH2:11]([Si@H:4]1[CH2:5][CH2:6][C@H:7]([C:18]2[CH:23]=[CH:22][C:21]([C:18]3[CH:23]=[CH:22][C:21]([O:24][C:25]([F:29])=[C:26]([F:28])[F:27])=[C:20]([F:30])[CH:19]=3)=[C:20]([F:30])[CH:19]=2)[CH2:8][CH2:9]1)[CH2:16][CH3:15]

Participants

3

Reactant 2

HCID 118313174-Propyl-4-phenyl-4-silacyclohexanoneHCID 189357584-Bromo-2-fluoro-1-(1,2,2-trifluorovinyloxy)benzene

Product 1

HCID 178418243HCID 178418243, compound

Procedure

The general procedure of Example 36 was repeated using 4-propyl-4-phenyl-4-silacyclohexanone instead of 4-pentyl-4-phenyl-4-silacyclohexanone and 4-bromo-2-fluoro-1-(1,2,2-trifluorovinyloxy)benzene instead of 4-bromo-2,6-difluoro-1-(1,2,2-trifluorovinyl)benzene, thereby obtaining the intended compound.

Workup

  1. customobtaining the intended compound

Sources & evidence

ORD record
ord-a5876763371f4e2ba7a63c3d5338778c
Source dataset
uspto-grants-1998_03
Patent number
US05730901

Reaction notes

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