HRID265913

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=C1OC(=O)c2cc(-c3ccc4c(c3)C(=O)OC4=O)ccc21

HCID75494

4,4′-Biphenyltetracarboxylic dianhydride

C16H6O6

结构：Nc1ccc(-c2ccc(N)cc2C(F)(F)F)c(C(F)(F)F)c1

HCID629349

2,2'-Bis(trifluoromethyl)benzidine

C14H10F6N2

PRODUCTS

生成物

结构：Nc1ccc(-c2ccc(N)cc2C(F)(F)F)c(C(F)(F)F)c1.O=C1OC(=O)c2cc(-c3ccc4c(c3)C(=O)OC4=O)ccc21

HCID131720099

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID13387

N-Methyl-2-pyrrolidone

C5H9NO

PROCEDURE

实验过程

A solution of polyamic acid was prepared at room temperature by combining 4.853 grams of 6FDA, 3.200 grams of BPDA, 6.967 grams of TFMB and 62.1 grams of NMP with good mixing. The amic acid solution was diluted to 10.9% solids, then cast on a silicon wafer by spin coating, and imidized by a heat treatment up to a maximum temperature of 300° C. to produce a coating having a thickness of 2.1 microns. The refractive index was determined in the same manner as in Example 1 and is reported in Table I.

WORKUP

后处理

customA solution of polyamic acid was prepared at room temperature
customimidized by a heat treatment up to a maximum temperature of 300° C.
customto produce a coating

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b37d2905e38146968b8c5b5cf707a1a6
来源数据集: uspto-grants-1997_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05649045
来源说明: uspto-grants-1997_07

反应 SMILES

[CH:1]1[C:6]([C:7]2[CH:12]=[CH:11][C:10]3[C:13]([O:15][C:16](=[O:17])[C:9]=3[CH:8]=2)=[O:14])=[CH:5][C:4]2[C:18]([O:20][C:21](=[O:22])[C:3]=2[CH:2]=1)=[O:19].[CH:23]1[C:28]([NH2:29])=[CH:27][C:26]([C:30]([F:33])([F:32])[F:31])=[C:25]([C:34]2[CH:39]=[CH:38][C:37]([NH2:40])=[CH:36][C:35]=2[C:41]([F:44])([F:43])[F:42])[CH:24]=1>CN1C(=O)CCC1>[CH:1]1[C:6]([C:7]2[CH:12]=[CH:11][C:10]3[C:13]([O:15][C:16](=[O:17])[C:9]=3[CH:8]=2)=[O:14])=[CH:5][C:4]2[C:18]([O:20][C:21](=[O:22])[C:3]=2[CH:2]=1)=[O:19].[CH:38]1[C:37]([NH2:40])=[CH:36][C:35]([C:41]([F:44])([F:42])[F:43])=[C:34]([C:25]2[CH:24]=[CH:23][C:28]([NH2:29])=[CH:27][C:26]=2[C:30]([F:31])([F:32])[F:33])[CH:39]=1