Ethyl 4-(4-acetyl-8-acetoxytridecyl)benzoate → HCID 20386075, compound

HRID 26610Notes

Reaction equation

HRID 26610 reaction equation
[C:1]([CH:4]([CH2:19][CH2:20][CH2:21][CH:22]([O:28]C(=O)C)[CH2:23][O:24][CH2:25][CH2:26][CH3:27])[CH2:5][CH2:6][CH2:7][C:8]1[CH:18]=[CH:17][C:11]([C:12]([O:14]CC)=[O:13])=[CH:10][CH:9]=1)(=[O:3])[CH3:2].C(C(CCCC(OC(=O)C)CCCCC)CCCC1C=CC(C(OCC)=O)=CC=1)(=O)C>>[C:1]([CH:4]([CH2:19][CH2:20][CH2:21][CH:22]([OH:28])[CH2:23][O:24][CH2:25][CH2:26][CH3:27])[CH2:5][CH2:6][CH2:7][C:8]1[CH:18]=[CH:17][C:11]([C:12]([OH:14])=[O:13])=[CH:10][CH:9]=1)(=[O:3])[CH3:2]

Participants

3

Reactant 2

HCID 20386101Ethyl 4-(4-acetyl-8-acetoxytridecyl)benzoateHCID 20386129HCID 20386129, compound

Product 1

HCID 20386075HCID 20386075, compound

Procedure

This compound is prepared by the method described in Example 1, Step F, except that the product of Step C of the present example replaces ethyl 4-(4-acetyl-8-acetoxytridecyl)benzoate. The title compound is purified by column chromatography on silica gel with 4% methanol in chloroform as the eluant. The title compound is a light yellow, viscous oil.

Workup

  1. customThis compound is prepared by the method
  2. customThe title compound is purified by column chromatography on silica gel with 4% methanol in chloroform as the eluant

Sources & evidence

ORD record
ord-78a9f11cb0714561a8b1dcedd5745f70
Source dataset
uspto-grants-1979_04
Patent number
US04150235

Reaction notes

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