HRID266406

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID962

Water

H2O

HCID8793

N,N'-Dibenzylethane-1,2-diamine

C16H20N2

结构：CC(=O)N[C@@H](CSSC[C@H](NC(C)=O)C(=O)O)C(=O)O

HCID6995101

未命名化合物

PRODUCTS

生成物

结构：CC(=O)N[C@@H](CSSC[C@H](NC(C)=O)C(=O)[O-])C(=O)[O-].c1ccc(C[NH2+]CC[NH2+]Cc2ccccc2)cc1

HCID131718839

未命名化合物

PROCEDURE

实验过程

To a 63% solution of N,N'-diacetyl-L-cystine in water (67 mmole, 21.8 g) was added N,N'-dibenzylethylenediamine (67 mmole, 16.0 g). The exothermic reaction gave a slightly oily product which could be recrystallised from water to give 12.0 g (32%) of the title substance as white crystalline needles.

WORKUP

后处理

customThe exothermic reaction
customgave a slightly oily product which
customcould be recrystallised from water
customto give 12.0 g (32%) of the title substance as white crystalline needles

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-213eac77706449149dfd35b7a8250e1c
来源数据集: uspto-grants-1997_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05650538
来源说明: uspto-grants-1997_07

反应 SMILES

[C:1]([NH:4][C@H:5]([C:18]([OH:20])=[O:19])[CH2:6][S:7][S:8][CH2:9][C@H:10]([NH:14][C:15](=[O:17])[CH3:16])[C:11]([OH:13])=[O:12])(=[O:3])[CH3:2].O.[CH2:22]([NH:29][CH2:30][CH2:31][NH:32][CH2:33][C:34]1[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=1)[C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1>>[CH2:22]([NH2+:29][CH2:30][CH2:31][NH2+:32][CH2:33][C:34]1[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=1)[C:23]1[CH:24]=[CH:25][CH:26]=[CH:27][CH:28]=1.[C:15]([NH:14][C@H:10]([C:11]([O-:13])=[O:12])[CH2:9][S:8][S:7][CH2:6][C@H:5]([NH:4][C:1](=[O:3])[CH3:2])[C:18]([O-:20])=[O:19])(=[O:17])[CH3:16]