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HRID26656

反应详情

EQUATION

反应方程式

HRID 26656 的结构方程式

REACTANTS

反应物

2
结构：CO
HCID887

Methanol

CH4O

结构：CC(C(=O)O)P(=O)(O)O
HCID73187

2-Phosphonopropanoic acid

C3H7O5P

PRODUCTS

生成物

1
结构：COC(=O)C(C)P(=O)(O)O
HCID18623049

未命名化合物

PROCEDURE

实验过程

A solution of 2-phosphonopropionic acid (11.2 g., 0.073 moles) in methanol (150 ml.) is heated at reflux for eighteen hours. The methanol is removed in vacuo. Electrophoresis (0.1 N NH4HCO3, 2000 V, 20 minutes, 7.5 cm) indicates complete conversion to the desired product, methyl 2-phosphonopropionate; yield quantitative.

WORKUP

后处理

  1. temperatureat reflux for eighteen hours
  2. customThe methanol is removed in vacuo
  3. customElectrophoresis (0.1 N NH4HCO3, 2000 V, 20 minutes, 7.5 cm)
  4. customyield quantitative