Potassium Hydroxide → 2-Benzyl-4-nitroaniline

HRID 267281Notes

Reaction equation

HRID 267281 reaction equation
[NH2:1][C:2]1[CH:16]=[CH:15][C:14]([N+:17]([O-:19])=[O:18])=[CH:13][C:3]=1[C:4](=NN)[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[OH-].[K+]>C(O)COCCO>[CH2:4]([C:3]1[CH:13]=[C:14]([N+:17]([O-:19])=[O:18])[CH:15]=[CH:16][C:2]=1[NH2:1])[C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][CH:10]=1

Participants

4

Reactant 2

HCID 14797Potassium HydroxideHCID 783883702-Amino-5-nitrobenzophenone hydrazone

Product 1

HCID 214974002-Benzyl-4-nitroaniline

Reagents, catalysts & solvents 1

HCID 8117Diethylene GlycolSolvent

Procedure

In the manner given in Preparation 11, 2-amino-5-nitrobenzophenone hydrazone is refluxed with potassium hydroxide in diethylene glycol to give 2-benzyl-4-nitroaniline.

Sources & evidence

ORD record
ord-7baaaec357da46a6aa80301142dac7b3
Source dataset
uspto-grants-1976_03
Patent number
US03941802

Reaction notes

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