Jones' reagent → Benzophenone

HRID 267287Notes

Reaction equation

HRID 267287 reaction equation
FC(F)(F)[C:3]1[CH:8]=[CH:7][C:6]([CH2:9][C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[C:5](N2C=CN=C2)[CH:4]=1.CC(C)=[O:25].OS(O)(=O)=O.O=[Cr](=O)=O>C(O)(=O)C>[C:9]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=[O:25])[C:6]1[CH:7]=[CH:8][CH:3]=[CH:4][CH:5]=1

Participants

4

Reactant 2

HCID 131709961Jones' reagentHCID 131710077HCID 131710077, compound

Product 1

HCID 3102Benzophenone

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

In the manner given in Example 24, 1-[4-(trifluoromethyl)-α-phenyl-0-tolyl]imidazole in acetic acid is heated with Jones' reagent to give 5-(trifluoromethyl)-2-imidazo-1-yl)benzophenone.

Sources & evidence

ORD record
ord-1b28df7e36b1468f881db5f6bd11fc3f
Source dataset
uspto-grants-1976_03
Patent number
US03941802

Reaction notes

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