HCID 21556903, compound → 5-nitro-2-hexanone

HRID 267312Notes

Reaction equation

HRID 267312 reaction equation
[N+]([CH2:4][C:5](C)([OH:13])[CH2:6][CH2:7][CH:8]([N+:10]([O-:12])=[O:11])[CH3:9])([O-])=O>C1C=CC=CC=1>[N+:10]([CH:8]([CH3:9])[CH2:7][CH2:6][C:5](=[O:13])[CH3:4])([O-:12])=[O:11]

Participants

3

Reactant 1

HCID 21556903HCID 21556903, compound

Product 1

HCID 106306355-nitro-2-hexanoneYield 45.3%

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

To a solution of 0.91 gram of 1,5-dinitro-2-methyl-2-hexanol in 25 milliliters of benzene there was added 4.2 grams of alumina. The mixture was stirred for 24 hours, and the alumina was removed by filtration. After evaporation of the filtrate there was obtained 0.29 gram of 5-nitro-2-hexanone which was identified by infrared and proton magnetic resonance.

Workup

  1. customthe alumina was removed by filtration
  2. customAfter evaporation of the filtrate there

Sources & evidence

ORD record
ord-a1ec2d07712f4be1ad68c7b6ff1c2dd1
Source dataset
uspto-grants-1976_03
Patent number
US03941846

Reaction notes

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