HCID 21555504, compound → HCID 20361117, compound

HRID 267332Notes

Reaction equation

HRID 267332 reaction equation
C(C1(CC)C2CCCC=2C2C([O:21][C:22](=[O:32])[CH2:23][CH2:24][CH2:25][N:26]3[CH2:31][CH2:30][CH2:29][CH2:28][CH2:27]3)=CC(CCCCC)=CC=2O1)C.[CH2:35](C1C=C(OC(=O)CCCN2CCSCC2)C2C3C=C(C)CCC3C(C)(C)OC=2C=1)CCCC.C(C1C=C(OC(=O)CCN2CCCC2)C2C3CC(C)=CCC3C(C)(C)OC=2C=1)CCCC.O1CCN(CCCC(OC2C3C4CCCCC4COC=3C=C(CCCCC)C=2)=O)CC1>>[CH3:35][CH:23]([CH2:24][CH2:25][N:26]1[CH2:27][CH2:28][CH2:29][CH2:30][CH2:31]1)[C:22]([OH:21])=[O:32]

Participants

5

Reactant 4

HCID 21555504HCID 21555504, compoundHCID 21555505HCID 21555505, compoundHCID 21555506HCID 21555506, compoundHCID 86733107HCID 86733107, compound

Product 1

HCID 20361117HCID 20361117, compound

Procedure

Some of the compounds produced according to the invention are: 4,4-diethyl-7-n-pentyl-9-[4-(piperidino)-butyryloxy]-1,2,3,4-tetrahydrocyclopenta[c][1]benzopyran, 4,4-di-(1-hexyl)-7-(3-methyl-2-octyl)-9-[4-(morpholino)-butyryloxy]-1,2,3,4,12,13-hexahydrocyclopenta[c][1]benzopyran, 4,4-dimethyl-7-(3-methyl-2-octyl)-9-[4-(piperidino)-butyryloxy]-1,2,3,4,12,13-hexahydrocyclopenta[c][1]benzopyran, 4,4-diethyl-7-octadecyl-9-[3-pyrrolidino)-propionyloxy]-1,2,3,4,12,13-hexahydrocyclopenta[c][1]benzopyran, 3-pentyl-1-[4-(thiomorpholino)-butyryloxy]6a,7,8,10a-tetrahydro-6,6,9-trimethyl-6H-dibenzo[b,d]pyran, 3-pentyl-1-[3-(pyrrolidino)-propionyloxy]-6a,7,10,10a-tetrahydro-6,6,9-trimethyl-6H-dibenzo[b,d]pyran, 1-[4-(homopiperidino)-butyryloxy]-7,8,9,10-tetrahydro-6H-dibenzo-[b,d]pyran and 1-[4-(morpholino)-butyryloxy]-3-pentyl-6a, 7,8,9,10,10a hexahydro-6H-dibenzo[b,d]pyran.

Workup

  1. customSome of the compounds produced

Sources & evidence

ORD record
ord-8e1eec840b3547e0b959d8b123fb806a
Source dataset
uspto-grants-1976_03
Patent number
US03941782

Reaction notes

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