Methyl iodide → HCID 21556140, compound

HRID 267373Notes

Reaction equation

HRID 267373 reaction equation
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]1[CH:13]=[CH:12][C:11]([CH:14]([OH:20])[C:15]([O:17][CH2:18][CH3:19])=[O:16])=[CH:10][CH:9]=1.[CH3:21]I>N1C=CC=CC=1>[CH3:21][NH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]1[CH:13]=[CH:12][C:11]([CH:14]([OH:20])[C:15]([O:17][CH2:18][CH3:19])=[O:16])=[CH:10][CH:9]=1

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 21556032HCID 21556032, compound

Product 1

HCID 21556140HCID 21556140, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

To a solution of 0.01 moles of ethyl 2'-amino-4-biphenylylglycolate in 100 ml. of pyridine is added 0.1 moles of methyl iodide. The reaction mixture is stirred overnight at room temperature, filtered and concentrated. The residue is distilled to obtain ethyl 2'-methylamino-4-biphenylylglycolate.

Workup

  1. filtrationfiltered
  2. concentrationconcentrated
  3. distillationThe residue is distilled

Sources & evidence

ORD record
ord-e9af91ec5c724bb6a8e7e41bd25e026b
Source dataset
uspto-grants-1976_03
Patent number
US03941821

Reaction notes

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