α,4′-Dihydroxy[1,1′-biphenyl]-4-acetic acid → HCID 21556546, compound

HRID 267377Notes

Reaction equation

HRID 267377 reaction equation
N[C:2]1[CH:3]=[C:4]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[CH:5]=[CH:6][C:7]=1[CH:8]([OH:14])[C:9]([O:11]CC)=[O:10].NC1C=CC(C2C=CC(C(O)C(OCC)=[O:36])=CC=2)=CC=1.OC1C=C(C2C=CC=CC=2)C=CC=1C(O)C(O)=O.OC1C=CC(C2C=CC(C(O)C(O)=O)=CC=2)=CC=1>>[OH:36][C:16]1[CH:17]=[CH:18][CH:19]=[CH:20][C:15]=1[C:4]1[CH:5]=[CH:6][C:7]([CH:8]([OH:14])[C:9]([OH:11])=[O:10])=[CH:2][CH:3]=1

Participants

5

Reactant 4

HCID 19793114α,4′-Dihydroxy[1,1′-biphenyl]-4-acetic acidHCID 21556065HCID 21556065, compoundHCID 21556244HCID 21556244, compoundHCID 21556325HCID 21556325, compound

Product 1

HCID 21556546HCID 21556546, compound

Procedure

When ethyl 3-amino-4-biphenylylglycolate or ethyl 4'-amino-4-biphenylylglycolate are used in the above procedure then the product prepared is 3-hydroxy-4-biphenylylglycolic acid or 4'-hydroxy-4-biphenylylglycolic acid.

Workup

  1. customthe product prepared

Sources & evidence

ORD record
ord-642b6d737e1d47418adcd73baa8e5635
Source dataset
uspto-grants-1976_03
Patent number
US03941821

Reaction notes

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