Ammonia → Ammonia

HRID 267567Notes

Reaction equation

HRID 267567 reaction equation
[CH3:1][Si:2]([CH3:5])([CH3:4])Cl.[Br:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][OH:13].[NH3:14]>C1C=CC=CC=1>[NH3:14].[Br:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][O:13][Si:2]([CH3:5])([CH3:4])[CH3:1]

Participants

6

Reactant 3

HCID 222AmmoniaHCID 6397ChlorotrimethylsilaneHCID 779706-Bromo-1-hexanol

Product 2

HCID 222AmmoniaHCID 557911Silane, [(6-bromohexyl)oxy]trimethyl-

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

13.8 G. of trimethylchlorosilane and 11.4 g. of 6-bromohexan-1-ol are mixed together in 100 ml. of dry benzene and are stirred in an ice-bath while anhydrous ammonia is passed therethrough until the odor of ammonia persists to obtain 6-bromohexyloxytrimethylsilane, which is worked up by filtration, followed by evaporation of the filtrate and distillation in vacuo.

Sources & evidence

ORD record
ord-a3df633beccd4eadbe29718125365561
Source dataset
uspto-grants-1976_03
Patent number
US03943157

Reaction notes

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