Imidazole → [(6-Chlorohexyl)oxy](1,1-dimethylethyl)dimethylsilane

HRID 267568Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 267568
[CH3:1][Si:2]([CH3:8])([C:4]([CH3:7])([CH3:6])[CH3:5])Cl.[Cl:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][OH:16].N1C=CN=C1>CN(C)C=O>[Cl:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][O:16][Si:2]([CH3:8])([CH3:1])[C:4]([CH3:7])([CH3:6])[CH3:5]

Komponenten

5

Edukt 3

HCID 795ImidazoleHCID 28928tert-Butyldimethylsilyl chlorideHCID 748286-Chloro-1-hexanol

Produkt 1

HCID 10083489[(6-Chlorohexyl)oxy](1,1-dimethylethyl)dimethylsilane

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6228DimethylformamideLösungsmittel

Versuchsvorschrift

To 33 g. of dimethyl-tert-butylchlorosilane in 100 ml. of dimethylformamide is added 27 g. of 6-chlorohexan-1-ol and 340 g. of imidazole. The reaction mixture is allowed to stand at room temperature for 3 days to yield 6-chlorohexyloxy-dimethyl-tert-butylsilane, which is worked up by pouring into water, extracting with ether, washing with water, drying over calcium sulfate, removing the solvent by evaporation and purifying by distillation.

Quellen und Nachweise

ORD-Eintrag
ord-51e7c3f1df774dc0ae1737b6edcaaadb
Quelldatensatz
uspto-grants-1976_03
Patentnummer
US03943157

Notizen zur Reaktion

Wird geladen…