HuagongsheHuagongshe Chemistry Print Report · For research reference only
Pyridine → 3-[4-(2,4,6-TRI-ISOPROPYLBENZENESULFONAMIDO)BENZENESULFONYL]acrylonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Pyridine | HCID 1049 | — |
| Reactant | 2,4,6-Tris(1-methylethyl)benzenesulfonyl chloride | HCID 81042 | — |
| Reactant | 2-Cyanovinyl 4-aminophenyl sulfone | HCID 54561326 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | 3-[4-(2,4,6-TRI-ISOPROPYLBENZENESULFONAMIDO)BENZENESULFONYL]acrylonitrile | HCID 54159099 | — |
Reaction Steps
a solution of 9.1 g (0.03 mol) of 2,4,6-tri-isopropylbenzenesulfonyl chloride in 50 ml dioxane is added at room temperature to a solution of 6.3 g (0.03 mol) of 3-(4-aminobenzenesulfonyl)acrylonitrile in 150 ml dioxane, the dioxane solution additionally containing 3 ml (0.03 mol) of pyridine. After 8 hours the reaction mixture is filtered and evaporated and a tannish solid consisting of 3-[4-(2,4,6-tri-isopropylbenzenesulfonamido)benzenesulfonyl]acrylonitrile is obtained: ##SPC19##
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03943154 |
| Source dataset | uspto-grants-1976_03 |
| ORD ID | ord-f02845ccba3d4df58b9bdf159a52064e |
| Source note | uspto-grants-1976_03 |