2,4-Dichlorophenol → Benzyl Alcohol

HRID 267719Notes

Reaction equation

HRID 267719 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[CH:4][C:3]=1[OH:9].Br[CH2:11][CH:12]=[C:13]([CH3:20])[CH2:14][CH2:15][CH:16]=[C:17]([CH3:19])[CH3:18]>>[CH3:20][C:13]([CH2:14][CH2:15][CH:16]=[C:17]([CH3:19])[CH3:18])=[CH:12][CH2:11][O:9][C:3]1[CH:4]=[CH:5][C:6]([Cl:8])=[CH:7][C:2]=1[Cl:1].[CH2:20]([OH:9])[C:13]1[CH:14]=[CH:15][CH:16]=[CH:17][CH:19]=1

Participants

4

Reactant 2

HCID 84492,4-DichlorophenolHCID 802281-Bromo-3,7-dimethylocta-2,6-diene

Product 2

HCID 244Benzyl AlcoholHCID 68124233HCID 68124233, compound

Procedure

In a manner analogous to Example 8, 2,4-dichloro-phenol is reacted with 1-bromo-3,7-dimethyl-octa-2,6-diene to produce 2,4-dichloro-phenyl 3,7-dimethyl-octa-2,6-dienyl ether (nD25 = 1.5368) and benzyl alcohol is reacted with 1-bromo- 3,7-dimethyl-octa-2,6-diene to produce 3,7-dimethyl-octa-2,6-dienyl ether (nD25 = 1.5095).

Sources & evidence

ORD record
ord-d4fd27dcc147416ca8d7564fe4fcf0e8
Source dataset
uspto-grants-1976_03
Patent number
US03944531

Reaction notes

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