Methyl Vanillate → 4-[(1,5-Dimethyl-hexyl)-oxy]-m-methoxy-benzoic acid methyl ester

HRID 267725Notes

Reaction equation

Br[CH:2]([CH2:4][CH2:5][CH2:6][CH:7]([CH3:9])[CH3:8])[CH3:3].[CH3:10][O:11][C:12](=[O:22])[C:13]1[CH:21]=[CH:20][C:18]([OH:19])=[C:15]([O:16][CH3:17])[CH:14]=1>>[CH3:10][O:11][C:12](=[O:22])[C:13]1[CH:21]=[CH:20][C:18]([O:19][CH:2]([CH3:3])[CH2:4][CH2:5][CH2:6][CH:7]([CH3:9])[CH3:8])=[C:15]([O:16][CH3:17])[CH:14]=1

Participants

Reactant 2

HCID 19844Methyl Vanillate

HCID 1383322-Bromo-6-methylheptane

Product 1

HCID 539875924-[(1,5-Dimethyl-hexyl)-oxy]-m-methoxy-benzoic acid methyl ester

Procedure

By the procedure described in Example 1, 2-bromo-6-methyl-heptane is reacted with vanillic acid methyl ester to produce 4-[(1,5-dimethyl-hexyl)-oxy]-m-methoxy-benzoic acid methyl ester (boiling point = 198°-200°C/0.1 mmHg).

Sources & evidence

ORD record: ord-ac9708bfe2fe43c58744f3fd8c725bdb
Source dataset: uspto-grants-1976_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03944531

Reaction notes

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